Highly Efficient Sulfur and Nitrogen Codoped Graphene Quantum Dots as a Metal-Free Green Photocatalyst for Photocatalysis and Fluorescent Ink Applications
S. Tamizharasan, R. Muralidharan, N. Abirami, Leelavathi Harikrishnan, Kumarasamy Alwar, R. Arulmozhi
Abstract
The demand for modern organic pollutant treatment has prompted the development of environmentally acceptable photocatalytic processes. In this work, we report novel nitrogen and sulfur codoped graphene quantum dot (S,N-GQD) based photocatalysts and fluorescent ink for the first time. For the degradation of organic dyes under visible irradiation, a hydrothermal technique was employed to generate S,N-GQD green nanomaterials. The synthesized samples were examined using XRD, HR-TEM, EDX, FT-IR, PL, and UV-vis spectroscopy. UV-DRS was used to determine the energy band gap of S,N-GQDs, and it was obtained to be around ∼2.54 eV. To explore the catalytic behavior of the produced S,N-GQDs as green nanomaterials, organic dyes (i.e., crystal violet and Alizarin yellow) have been used as a reference dye in this study. Using several radical scavenging agents, the photocatalytic mechanism was examined. This novel photocatalyst offers a promising alternative for the breakdown of organic pollutants. Moreover, these S,N-GQDs can also be used as fluorescent ink for imaging purposes and security reasons.