Mechanistic Insights into the Role of Polydopamine Interlayer toward Improved Separation Performance of Polyamide Nanofiltration Membranes
Zhe Yang, Fei Wang, Hao Guo, Lu Elfa Peng, Xiao‐Hua Ma, Xiaoxiao Song, Zhiwei Wang, Chuyang Y. Tang
Abstract
). The TFNi membrane further showed enhanced rejection toward a wide range of inorganic salts and small organic molecules (including antibiotics and endocrine disruptors). Detailed mechanistic investigation reveals that the membrane separation performance was enhanced due to both the direct "gutter" effect of the PDA interlayer and its indirect effects resulting from enhanced polyamide formation on the PDA-coated substrate, with the "gutter" effect playing a more dominant role. This study provides a mechanistic and comprehensive framework for the future development of TFNi membranes.
Topics & Concepts
NanofiltrationMembranePermeancePolyamideThin-film composite membraneChemical engineeringReverse osmosisChemistrySelectivityMaterials scienceNanocompositeChromatographyPolymer chemistryOrganic chemistryPermeationBiochemistryCatalysisEngineeringMembrane Separation TechnologiesMembrane-based Ion Separation TechniquesGraphene and Nanomaterials Applications