Selective 1,2 addition of polar X–H bonds to the Ga–P double bond of gallaphosphene L(Cl)GaPGaL
Mahendra K. Sharma, Christoph Wölper, Stephan Schulz
Abstract
Gallaphosphene 1 reacts with a series of polar X–H bonds exclusively with 1,2 addition to the Ga–P double bond. The gallium atom serve as electrophile whereas the nucleophilic phosphorous atom is protonated by the H-acidic substrates.
Topics & Concepts
ChemistryHeteronuclear moleculeThiophenolCrystallographyGalliumDouble bondProtonationElectrophilePolarHydrogen bondMolybdenumStereochemistryMedicinal chemistryNuclear magnetic resonance spectroscopyInorganic chemistryMoleculeOrganic chemistryPhysicsIonCatalysisAstronomySynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisOrganoboron and organosilicon chemistry