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Machine‐Learning‐Driven G‐Quartet‐Based Circularly Polarized Luminescence Materials

Yankai Dai, Zhiwei Zhang, Dong Wang, Tianliang Li, Yuze Ren, Jingqi Chen, Lingyan Feng

2023Advanced Materials32 citationsDOI

Abstract

Abstract Circularly polarized luminescence (CPL) materials have garnered significant interest due to their potential applications in chiral functional devices. Synthesizing CPL materials with a high dissymmetry factor ( g lum ) remains a significant challenge. Inspired by efficient machine learning (ML) applications in scientific research, this work demonstrates ML‐based techniques for the first time to guide the synthesis of G‐quartet‐based CPL gels with high g lum values and multiple chiral regulation strategies. Employing an “experiment‐prediction‐verification” approach, this work devises a ML classification and regression model for the solvothermal synthesis of G‐quartet gels in deep eutectic solvents. This process illustrates the relationship between various synthesis parameters and the g lum value. The decision tree algorithm demonstrates superior performance across six ML models, with model accuracy and determination coefficients amounting to 0.97 and 0.96, respectively. The screened CPL gels exhibiting a g lum value up to 0.15 are obtained through combined ML guidance and experimental verification, among the highest ones reported till now for biomolecule‐based CPL systems. These findings indicate that ML can streamline the rational design of chiral nanomaterials, thereby expediting their further development.

Topics & Concepts

LuminescenceMaterials scienceEutectic systemBiomoleculeNanotechnologyNanomaterialsExpeditingArtificial intelligenceComputer scienceOptoelectronicsSystems engineeringComposite materialEngineeringAlloySynthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in MaterialsLuminescence and Fluorescent Materials
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