Alkali Metal Alkoxides in Noyori‐Type Hydrogenations
Pavel A. Dub
Abstract
Abstract This minireview discusses the accelerative role of alkali metal alkoxides in two important catalytic processes: hydrogenation of ketones and esters with Noyori‐type molecular catalysts. Here I offer my perspective on the unique mechanistic aspects of these reactions – a subject that remains controversial and often misunderstood.
Topics & Concepts
ChemistryCatalysisAlkali metalOrganic chemistryMetalNanotechnologyMaterials scienceAsymmetric Hydrogenation and CatalysisSurface Chemistry and CatalysisInnovative Microfluidic and Catalytic Techniques Innovation