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Polycondensation of bis(α-diazo-1,3-dicarbonyl) compounds with dicarboxylic acids: an efficient access to functionalized alternating polyesters

Xin Wang, Yuan‐Li Ding, Youhua Tao, Zikun Wang, Zhen Wang, Jingling Yan

2020Polymer Chemistry18 citationsDOI

Abstract

We report an efficient and mild approach to functionalized alternating polyesters on the basis of O–H insertion polycondensation of bis(α-diazo-1,3-dicarbonyl) compounds with dicarboxylic acids.

Topics & Concepts

PolyesterDiazoCondensation polymerDicarboxylic acidChemistryPolymer chemistryOrganic chemistryCatalysisCyclopropane Reaction MechanismsCatalytic Alkyne ReactionsCatalytic C–H Functionalization Methods
Polycondensation of bis(α-diazo-1,3-dicarbonyl) compounds with dicarboxylic acids: an efficient access to functionalized alternating polyesters | Litcius