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Rapid Kinetic Screening via Transient <i>Timesweep</i> Experiments in Continuous Flow Reactors

Joren Van Herck, Tanja Junkers

2021Chemistry - Methods20 citationsDOIOpen Access PDF

Abstract

Abstract Kinetic screenings and optimization of chemical reactions are of utmost importance to develop an understanding of underlaying reaction mechanisms. From a more practical point of view, they are needed to obtain a final product under the most efficient and optimal conditions possible. Flow chemistry and reaction automation are an excellent combination to reach these aims. Exploiting features of both concepts generate a highly efficient screening method. Monitoring the reaction during the transient stabilization from flow rate A to flow rate B results in a continuous sweep through all intermediate residence times. Real‐time analysis of the timesweeps gives a full kinetic profile of the chemical transformation carried out in the flow reactor.

Topics & Concepts

Transient (computer programming)Residence time (fluid dynamics)Kinetic energyProcess engineeringContinuous reactorFlow (mathematics)Volumetric flow rateComputer scienceResidence time distributionChemical reactionContinuous flowChemistryMaterials scienceBiochemical engineeringThermodynamicsMechanicsPhysicsEngineeringCatalysisOrganic chemistryGeotechnical engineeringQuantum mechanicsOperating systemInnovative Microfluidic and Catalytic Techniques InnovationMicrofluidic and Capillary Electrophoresis ApplicationsFluid Dynamics and Mixing