Mechanistic insights into rhodium-catalyzed enantioselective allylic alkylation for quaternary stereogenic centers
Monika Pareek, Raghavan B. Sunoj
Abstract
The origin of high enantioselectivity in the formation of quaternary stereogenic carbon.
Topics & Concepts
StereocenterEnantioselective synthesisRhodiumQuaternary carbonTsuji–Trost reactionAlkylationQuaternaryCatalysisChemistryStereochemistryCombinatorial chemistryOrganic chemistryBiologyPaleontologyAsymmetric Hydrogenation and CatalysisAsymmetric Synthesis and CatalysisCatalytic C–H Functionalization Methods