Sub- and super-Nernstian Tafel slopes can result from reversible electron transfer coupled to either preceding or following chemical reaction
Haotian Chen, Richard G. Compton
Topics & Concepts
Tafel equationChemistryElectron transferChemical reactionReversible reactionElectrochemistryContext (archaeology)KineticsLinear sweep voltammetryOrder of reactionChemical kineticsCyclic voltammetryReaction mechanismReaction rateReaction rate constantThermodynamicsElectrodePhysical chemistryOrganic chemistryCatalysisBiologyQuantum mechanicsPhysicsPaleontologyElectrochemical Analysis and ApplicationsMolecular Junctions and NanostructuresElectrocatalysts for Energy Conversion