Electrosynthesis of iminophosphoranes and applications in nickel catalysis
Velabo Mdluli, Dan Lehnherr, Yu‐hong Lam, Mohammad T. Chaudhry, Justin A. Newman, Jimmy DaSilva, Erik L. Regalado
Abstract
N -Cyano iminophosphoranes are synthesized using electrochemistry and evaluated as ligands in various nickel-catalysed reactions. The electronic and structural properties of these ligands were studied both computationally and experimentally.
Topics & Concepts
ElectrosynthesisNickelElectrochemistryChemistryCatalysisCombinatorial chemistryOrganic chemistryPhysical chemistryElectrodeCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques