Taming of Triazole, Tetrazole, and Azido Groups: Nitrogen-Rich Energetic Materials with High Thermal Stabilities
Yuhuang Peng, Qiong Yu, Wenbin Yi
Abstract
Nitrogen-rich energetic materials are of interest due to their potential use as high-energy-density materials in various applications. However, most compounds with a high nitrogen content show poor thermal stabilities, which may limit their use in certain applications. In pursuit of nitrogen-rich energetic materials, this study presents the synthesis and characterization of two nitrogen rich energetic compounds, namely 3-azido-1-(1 H -tetrazol-5-yl)-1 H -1,2,4-triazol-5-amine ( 3, C 3 H 3 N 11, N%: 79.78) and ( E )-1,2-bis(3-azido-1-(1 H -tetrazol-5-yl)-1 H -1,2,4-triazol-5-yl) diazene ( 7, C 6 H 2 N 22, N%: 80.62). Compounds 3 and 7 have high thermal stabilities of 216 and 221 °C, respectively, making them the most thermally stable among metal-free primary explosives. Additionally, they show good energetic performance ( v D: 8345 m s –1; P: 25.17 GPa; v D: 8275 m s –1; P: 25.57 GPa), making them potential candidates for metal-free high energy primary explosive. The energetic salts of 3 and 7 were also investigated. Among them, hydrazinium salt 11 displays better energetic performance ( v D: 9089 m s –1; P: 30.55 GPa), which was on par with those of cyclotetramethylene tetranitramine (HMX). This research contributes to the exploration of nitrogen-rich energetic materials with potential applications in various fields.