Improved enantioselectivity in thiol–ene photopolymerization of sulphur-containing polymers with circularly polarized luminescence
Chenlu He, Zeyu Feng, Yan Li, Manman Zhou, Liyang Zhao, Sizhen Shan, Mengqiao Wang, Xin Chen, Xi‐Sheng Wang, Gang Zou
Abstract
Optically active poly(thioether) are obtained based on CPL-triggered thiol–ene photopolymerization assisted with achiral HAD. The poly(thioether) exhibits clusterization-triggered emission and circularly polarized luminescence behavior.
Topics & Concepts
ThioetherPhotopolymerLuminescenceThiolSulfurEne reactionPolymerMaterials sciencePhotochemistryChemistryPolymer chemistryOrganic chemistryOptoelectronicsComposite materialPolymerizationSynthesis and Properties of Aromatic CompoundsLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistry