Chiroptical detection of a model ruthenium dye in water by circularly polarized-electrochemiluminescence
Silvia Voci, Francesco Zinna, Lorenzo Arrico, Stéphane Grass, Laurent Bouffier, Jérôme Lacour, Lorenzo Di Bari, Nešo Šojić
Abstract
-based dye by circularly polarized-electrochemiluminescence (CP-ECL). This new aspect of the ECL emission combines the chiral information intrinsic to CPL methods with an electrogeneration of the excited state. Thus, it opens the possibility to perform ECL-based bioassays or microscopy with efficient chiral dyes.
Topics & Concepts
ElectrochemiluminescenceRutheniumCircular polarizationEnantiomerPhotochemistryPhysicsMaterials scienceChemistryOpticsElectrodeStereochemistryPhysical chemistryOrganic chemistryCatalysisMicrostripAdvanced biosensing and bioanalysis techniquesDNA and Nucleic Acid ChemistryMolecular Sensors and Ion Detection