Modulating <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si1.svg"><mml:mrow><mml:msubsup><mml:mi>d</mml:mi><mml:mi>z</mml:mi><mml:mn>2</mml:mn></mml:msubsup></mml:mrow></mml:math>-orbital occupancy of Au cocatalysts for enhanced photocatalytic H2O2 production
Xiaofang Li, Zhigang Wang
Abstract
A NiS-induced electron transfer reversal is developed to optimize the d z 2 -orbital occupancy of active Au atoms for realizing highly selective H 2 O 2 evolution on core-shell NiS@Au cocatalysts.
Topics & Concepts
PhotocatalysisOccupancyMethylene blueChemistryProduction (economics)PhotochemistryCatalysisOrganic chemistryEngineeringEconomicsMacroeconomicsArchitectural engineeringCatalytic Processes in Materials ScienceAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in Catalysis