Phenolate anion-catalyzed direct activation of inert alkyl chlorides driven by visible light
Delian Wei, Xipan Li, Lei Shen, Yuzhen Ding, Kangjiang Liang, Chengfeng Xia
Abstract
A photochemical activation of inert alkyl chlorides catalyzed by phenolate anions was developed for C–O bond formation, dehalogenation, and cyclization under mild conditions.
Topics & Concepts
ChemistryAlkylInertCatalysisHalogenationPhotochemistryIonMedicinal chemistryPolymer chemistryOrganic chemistryRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques