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Canted antiferromagnetic order in EuZn2As2 single crystals

Z. Bukowski, Damian Rybicki, Michał Babij, J. Przewoźnik, Ł. Gondek, J. Żukrowski, Cz. Kapusta

2022Scientific Reports17 citationsDOIOpen Access PDF

Abstract

Abstract Compounds containing Eu show a vast range of unique physical properties due to the interplay of electronic and magnetic properties, which can lead to a nontrivial electronic topology combined with magnetic order. We report on the growth of trigonal ( $$P\overline{3 }m1$$ <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>P</mml:mi> <mml:mover> <mml:mn>3</mml:mn> <mml:mo>¯</mml:mo> </mml:mover> <mml:mi>m</mml:mi> <mml:mn>1</mml:mn> </mml:mrow> </mml:math> space group) EuZn 2 As 2 single crystals and on the studies of their structural, electronic and magnetic properties. A range of experimental techniques was applied including X-ray diffraction, electron microscopy, magnetic susceptibility, magnetization, heat capacity and Mössbauer spectroscopy in the study. We found that Eu has solely a 2+ valence state and its magnetic moments below T N = 19.2 K form a canted antiferromagnetic structure, tilted from the basal plane.

Topics & Concepts

AntiferromagnetismCondensed matter physicsMagnetizationBasal planeMagnetic momentMössbauer spectroscopyValence (chemistry)Magnetic susceptibilityMaterials scienceChemistryCrystallographyPhysicsMagnetic fieldOrganic chemistryQuantum mechanicsIron-based superconductors researchMagnetic and transport properties of perovskites and related materialsRare-earth and actinide compounds
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