Heteroleptic copper(<scp>i</scp>) complexes [Cu(dmp)(N^P)]BF<sub>4</sub> for photoinduced atom-transfer radical addition reactions
You-Hui Zhao, Haiyan Li, Haiyan Li, David James Young, Xiangqian Cao, Da‐Liang Zhu, Zhi‐Gang Ren, Hong-Xi Li, Hong-Xi Li
Abstract
to styrenes in yields up to 91% and with a broad substrate scope. The absorption, emission, redox potential and photocatalytic activity were dependent on the substituents on the phpz ligand. Mechanistic studies supported an atom-transfer radical addition (ATRA) mechanism.
Topics & Concepts
ChemistryCopperAtom (system on chip)PhotochemistryStereochemistryMedicinal chemistryOrganic chemistryComputer scienceEmbedded systemRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsCO2 Reduction Techniques and Catalysts