Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes
Yasuhiro Yamauchi, Yoichi Hoshimoto, Takahiro Kawakita, Takuya Kinoshita, Yuta Uetake, Hidehiro Sakurai, Sensuke Ogoshi
Abstract
-phosphine oxide substituents facilitates both the adsorption and desorption of CO on nickel(0) via ligand substitution. Ionic liquids were used as the reaction medium to enhance the desorption rate and establish a reusable system. These results showcase a way for the sustainable chemisorption of CO using a zero-valent transition-metal complex.
Topics & Concepts
ChemistryCarbon monoxideChemisorptionDesorptionNickelInorganic chemistryAdsorptionTransition metalCovalent bondLigand (biochemistry)OxideCarbenePhotochemistryCatalysisOrganic chemistryBiochemistryReceptorIonic liquids properties and applicationsCarbon dioxide utilization in catalysisCatalysis and Oxidation Reactions