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Room temperature lithium superionic conductivity in high entropy oxides

David Bérardan, Sylvain Franger, Abhishek Meena, Nita Dragoe

2016Journal of Materials Chemistry A756 citationsDOIOpen Access PDF

Abstract

Impedance spectroscopy measurements evidence superionic Li <sup>+</sup> mobility (&gt;10 <sup>−3</sup> S cm <sup>−1</sup> ) at room temperature and fast ionic mobility for Na <sup>+</sup> (5 × 10 <sup>−6</sup> S cm <sup>−1</sup> ) in high entropy oxides, a new family of oxide-based materials with the general formula (MgCoNiCuZn) <sub>1−x−y</sub> Ga <sub>y</sub> A <sub>x</sub> O (with A = Li, Na, K).

Topics & Concepts

Ionic conductivityElectrical resistivity and conductivityAnalytical Chemistry (journal)ConductivityLithium (medication)Fast ion conductorMaterials scienceChemistryCrystallographyInorganic chemistryPhysical chemistryPhysicsElectrolyteMedicineElectrodeEndocrinologyChromatographyQuantum mechanicsThermal Expansion and Ionic ConductivityHigh Entropy Alloys StudiesInorganic Chemistry and Materials
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