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Inducing large birefringence by enhancing asymmetric electron distribution of Y–O polyhedra

Mengen Gao, Qiang Bian, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

2022Inorganic Chemistry Frontiers21 citationsDOI

Abstract

In four Y-based borates, the Y–O groups have different spans of overlap population and the compounds exhibit various birefringence values, ranging from 0.038 to 0.103.

Topics & Concepts

BirefringencePolyhedronElectronBoronPopulationMaterials scienceDistribution (mathematics)CrystallographyRangingChemistryPhysicsMathematicsCombinatoricsOpticsGeographyOrganic chemistryDemographyNuclear physicsGeodesyMathematical analysisSociologyCrystal Structures and PropertiesInorganic Fluorides and Related CompoundsHigh-pressure geophysics and materials