Regio- and stereoselective manganese-catalyzed hydrosulfonylation of alkynes: facile access to <i>Z</i>-vinyl sulfones
Jian Han, Lili Zeng, Ronghui Huang, Xiao-Qing Feng, Fen‐Er Chen
Abstract
We have reported a concise and complementary approach for the synthesis of high-selectivity ( Z )-vinyl sulfones via a ligand-tuned metalloradical reactivity strategy.
Topics & Concepts
ChemistryStereoselectivityManganeseCatalysisSelectivityReactivity (psychology)Ligand (biochemistry)Combinatorial chemistryOrganic chemistryPathologyAlternative medicineMedicineReceptorBiochemistrySulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsCatalytic C–H Functionalization Methods