Synthesis of a palladium based MOF <i>via</i> an effective post-synthetic modification approach and its catalytic activity towards Heck type coupling reactions
Srinivasulu Parshamoni, Rajendar Nasani, Abhik Paul, Sanjit Konar
Abstract
The complete exchange of metal nodes in a MOF with the Pd(<sc>ii</sc>) ions was done without losing the structural integrity. The new MOF turned out to be an excellent catalyst for the C–C bond formation <italic>via</italic> un-reacted cleavage C–N bond of arylhydrazines.
Topics & Concepts
PalladiumCatalysisChemistryBond cleavageHeck reactionCombinatorial chemistryCleavage (geology)Coupling reactionPolymer chemistryOrganic chemistryMaterials scienceComposite materialFracture (geology)Metal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and ApplicationsCatalytic Cross-Coupling Reactions