Optical dichroism in ZnGeP<sub>2</sub> crystals at deep levels
G. A. Medvedkin
Abstract
Undoped single crystals <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">Z</mml:mi> <mml:mi mathvariant="normal">n</mml:mi> <mml:mi mathvariant="normal">G</mml:mi> <mml:mi mathvariant="normal">e</mml:mi> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">P</mml:mi> </mml:mrow> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> have been studied by optical absorption spectroscopy in the range of 0.65–3.0 µm, where the unwanted absorption by intrinsic point defects plays a decisive role in highly efficient nonlinear optical devices. An increased optical dichroism up to 70% is achieved due to rearrangement of deep levels after low-temperature annealing (LTA). Zinc vacancies among other defects (phosphorus vacancies, cationic antisites) make the main contribution to the local structure transformation. A surprising fact is that the amplitude of optical dichroism at the deep acceptor <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">V</mml:mi> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">Z</mml:mi> <mml:mi mathvariant="normal">n</mml:mi> </mml:mrow> </mml:mrow> </mml:msub> </mml:mrow> </mml:math> exceeds the maximum photopleochroism <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo>∼</mml:mo> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>55</mml:mn> </mml:mrow> </mml:mrow> <mml:mi mathvariant="normal">%</mml:mi> </mml:math> for direct optical transitions in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">Z</mml:mi> <mml:mi mathvariant="normal">n</mml:mi> <mml:mi mathvariant="normal">G</mml:mi> <mml:mi mathvariant="normal">e</mml:mi> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">P</mml:mi> </mml:mrow> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> . Structural improvement based on the distorted tetrahedron model is discussed.