Catalytic addition of C–H bonds across C–C unsaturated systems promoted by iridium(<scp>i</scp>) and its group IX congeners
David F. Fernández, José L. Mascareñas, Fernando López
Abstract
), as well as by the C-C unsaturated partner that is used as a hydrocarbonation partner (alkyne, allene or alkene). Importantly, we discuss the mechanistic foundations of the methods highlighting the differences from those previously proposed for processes catalyzed by related metals, particularly those of the same group (Co and Rh).
Topics & Concepts
IridiumCatalysisChemistryGroup (periodic table)Medicinal chemistryOrganic chemistryCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and CatalysisSynthesis and Catalytic Reactions