On the Importance of Ligand-Centered Excited States in the Emission of Cyclometalated Ir(III) Complexes
Iván Soriano-Díaz, Enrique Ortı́, Angelo Giussani
Abstract
minimum. The results constitute a significant case in which the emission from ligand-centered states is the key for determining the high emission quantum yield of a complex.
Topics & Concepts
ChemistryPhosphorescenceExcited stateQuantum yieldLigand (biochemistry)IridiumPhotochemistryAcetonitrileDensity functional theoryBipyridinePyridineTriplet stateMetalCrystallographyPhysical chemistryMoleculeComputational chemistryAtomic physicsFluorescenceCrystal structureMedicinal chemistryBiochemistryQuantum mechanicsCatalysisOrganic chemistryChromatographyReceptorPhysicsOrganic Light-Emitting Diodes ResearchOrganometallic Complex Synthesis and CatalysisMetal complexes synthesis and properties