Reversible Trace‐Water‐Buffering Frameworks for Efficient Humid Methane Purification
Cheng Chen, Ming Li, Shuixiang Zou, Wei Wei, Maochun Hong, Mingyan Wu
Abstract
Abstract Trace water is usually fatal to gas separation process because the adsorption sites of adsorbents can be readily devitalized under humid conditions. Here, we develop trace‐water‐buffering porous materials with reversible structural transformation triggered by water adsorption/desorption, achieving exceptional methane purification under humid conditions. Despite the different structures, both the hydrated and dehydrated materials show high adsorption capacities for bulky C 3 H 8 and intermediate‐sized C 2 H 6 molecules but low CH 4 uptake. Based on these unique properties, the dehydrated material achieves efficient separation of ternary CH 4 /C 2 H 6 /C 3 H 8 mixtures even under 100% relative humidity, delivering high‐purity CH 4 (>99.99%) with a remarkable yield of 7.2 mmol·g −1 . This work sheds light on the designed synthesis of a new generation of microporous materials with reversible water‐buffering performance for gas purification under practically humid conditions.