A calix[4]pyrrole-based linear supramolecular polymer constructed by orthogonal self-assembly
Aysegul Budak, Abdullah Aydogan
Abstract
A calix[4]pyrrole having a ureidopyrimidinone unit was successfully synthesized from its alcohol-functionalized congener and further used for the first time to obtain a thermo- and chemical-responsive linear supramolecular polymer via orthogonal self-assembly comprising a combination of quadruple hydrogen bonding and anion recognition.
Topics & Concepts
Supramolecular chemistrySupramolecular polymersPyrroleHydrogen bondPolymerMaterials scienceLinear polymerPolymer chemistrySupramolecular assemblyChemistryCrystallographyMoleculeCrystal structureOrganic chemistryComposite materialMolecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials