The electronic structure of FeV-cofactor in vanadium-dependent nitrogenase
Zhi‐Yong Yang, Emilio Jiménez‐Vicente, Hayden Kallas, Dmitriy Lukoyanov, Hao Yang, Julia S. Martín del Campo, Dennis R. Dean, Brian M. Hoffman, Lance C. Seefeldt
Abstract
Active site FeV-cofactor of the V-nitrogenase and the EPR spectrum of the reduced cofactor showing <sup>51</sup>V-hyperfine coupling.
Topics & Concepts
NitrogenaseCofactorVanadiumElectron paramagnetic resonanceHyperfine structureChemistryHyperfine couplingElectronic structureCoupling (piping)StereochemistryPhotochemistryCrystallographyNuclear magnetic resonanceMaterials scienceInorganic chemistryEnzymeBiochemistryPhysicsComputational chemistryNitrogen fixationAtomic physicsOrganic chemistryMetallurgyNitrogenMetalloenzymes and iron-sulfur proteinsElectrocatalysts for Energy ConversionCatalytic Processes in Materials Science