Distance Effect of Ni-Pt Dual Sites for Active Hydrogen Transfer in Tandem Reaction
Huibin Wu, Bin Zhang, Haojie Liang, Liming Zhai, Guofu Wang, Yong Qin
Abstract
interlayer provide the active sites for hydrogen transfer with -Ti-OH surface intermediates via the continuous chemisorption/desorption of water. A smaller distance induces the generation of more active sites for hydrogen transfer and thus higher efficiency in the synergy of Ni and Pt sites. Our work provides new insight for the distance effect of different active sites and the mechanism of intermediate transfer in tandem reactions.
Topics & Concepts
CatalysisHydrogenChemical engineeringTandemChemistryDesorptionChemisorptionMaterials scienceInorganic chemistryAdsorptionPhysical chemistryOrganic chemistryComposite materialEngineeringCatalytic Processes in Materials ScienceNanomaterials for catalytic reactionsElectrocatalysts for Energy Conversion