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A 0D hybrid lead-free halide with near-unity photoluminescence quantum yield toward multifunctional optoelectronic applications

Dongyang Li, Huai-Yuan Kang, Yuhang Liu, Jie Zhang, Cheng‐Yang Yue, Dongpeng Yan, Xiao‐Wu Lei

2023Chemical Science65 citationsDOIOpen Access PDF

Abstract

), ultra-high spatial resolution of 17.25 lp per mm and negligible afterglow time (0.48 ms) demonstrate its excellent application prospects in X-ray imaging. In addition, this 0D halide also exhibits reversible luminescence off-on switching toward tribromomethane (TBM) but fails in any other organic solvents with an ultra-low detection limit of 0.1 ppm, acting as a perfect real-time fluorescent probe to detect TBM with ultrahigh sensitivity, selectivity and repeatability. Therefore, this work highlights the multiple optoelectronic applications of 0D hybrid lead-free halides in white LEDs, X-ray scintillation, fluorescence sensors,

Topics & Concepts

HalideQuantum yieldIndiumOptoelectronicsPhotoluminescenceMaterials scienceFluorescenceAbsorption (acoustics)Absorption edgeOpticsChemistryPhysicsInorganic chemistryBand gapComposite materialPerovskite Materials and ApplicationsLuminescence and Fluorescent MaterialsLuminescence Properties of Advanced Materials