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Covalent–Organic Frameworks: Advanced Organic Electrode Materials for Rechargeable Batteries

Tao Sun, Jian Xie, Wei Guo, Dong‐Sheng Li, Qichun Zhang

2020Advanced Energy Materials615 citationsDOI

Abstract

Abstract Covalent–organic frameworks (COFs), featuring structural diversity, framework tunability and functional versatility, have emerged as promising organic electrode materials for rechargeable batteries and garnered tremendous attention in recent years. The adjustable pore configuration, coupled with the functionalization of frameworks through pre‐ and post‐synthesis strategies, enables a precise customization of COFs, which provides a novel perspective to deepen the understanding of the fundamental problems of organic electrode materials. In this review, a summary of the recent research into COFs electrode materials for rechargeable batteries including lithium‐ion batteries, sodium‐ion batteries, potassium‐ion batteries, and aqueous zinc batteries is provided. In addition, this review will also cover the working principles, advantages and challenges, strategies to improve electrochemical performance, and applications of COFs in rechargeable batteries.

Topics & Concepts

Materials scienceNanotechnologyOrganic radical batteryLithium (medication)Surface modificationElectrodeElectrochemistryBattery (electricity)Chemical engineeringEngineeringChemistryPhysical chemistryQuantum mechanicsMedicinePhysicsPower (physics)EndocrinologyAdvanced battery technologies researchCovalent Organic Framework ApplicationsAdvancements in Battery Materials
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