1T′‐ReS<sub>2</sub> Nanosheets In Situ Grown on Carbon Nanotubes as a Highly Efficient Polysulfide Electrocatalyst for Stable Li–S Batteries
Jiarui He, Amruth Bhargav, Hooman Yaghoobnejad Asl, Yuanfu Chen, Arumugam Manthiram
Abstract
Abstract The practical viability of Li–S cells depends on achieving high electrochemical utilization of sulfur under realistic conditions, such as high sulfur loading and low electrolyte/sulfur (E/S) ratio. Here, metallic 2D 1T′‐ReS 2 nanosheets in situ grown on 1D carbon nanotubes (ReS 2 @CNT) via a facile hydrothermal reaction are presented to efficiently suppress the “polysulfide shuttle” and promote lithium polysulfide (LiPS) redox reactions. The designed ReS 2 @CNT nanoarchitecture with high conductivity and rich nanoporosity not only facilitates electron transfer and ion diffusion, but also possesses abundant active sites providing high catalytic activity for efficient LiPS conversion. Li–S cells fabricated with ReS 2 @CNT exhibit high capacity with superior long‐term cyclability with a capacity retention of 71.7% over 1000 cycles even at a high current density of 1C (1675 mA g −1 ). Also, pouch cells fabricated with the ReS 2 @CNT/S cathode maintain a low capacity fade rate of 0.22% per cycle. Furthermore, the electrocatalysis mechanism is revealed based on electrochemical studies, theoretical calculations, and in situ Raman spectroscopy.