Visible light promoted polyhalomethylation of alkenes: alkylation and cyclization
Tong-Lin Wang, Bo‐Sheng Zhang, Jingjiang Liu, Xiaojun Liu, Xi‐Cun Wang, Zheng‐Jun Quan
Abstract
The report describes a visible light promoted carbochloromethylation of 2-bromomethyl acrylate and N -arylmethacrylamide, and a series of trihalomethyl substituted allylic acid esters and indolone derivatives were synthesized.
Topics & Concepts
ChemistryAlkylationAcrylateAllylic rearrangementTsuji–Trost reactionVisible spectrumOrganic chemistryMedicinal chemistryCatalysisPolymerMonomerOptoelectronicsPhysicsRadical Photochemical ReactionsFluorine in Organic ChemistryOxidative Organic Chemistry Reactions