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Terminology of Electrochemiluminescence Reaction Mechanisms

Paul S. Francis, Sara Knežević, Conor F. Hogan, Nešo Šojić

2025ACS electrochemistry.17 citationsDOIOpen Access PDF

Abstract

We examine the terminology applied to the electron-transfer reaction mechanisms of annihilation and coreactant electrochemiluminescence (ECL) systems and introduce an alternative approach based on the reaction that ultimately generates the excited state of the luminophore. The terminology is derived from photochemistry and electrochemistry terms, enabling more consistent, intuitive labeling of excitation, catalytic, and quenching routes.

Topics & Concepts

TerminologyElectrochemiluminescenceComputer scienceNatural language processingLinguisticsPhilosophyChemistryChromatographyDetection limitAdvanced biosensing and bioanalysis techniquesElectrochemical Analysis and ApplicationsRNA and protein synthesis mechanisms