New Strategy to Build a High-Performance P′2-Type Cathode Material through Oxygen Vacancies and Mg Substitution for Sodium-Ion Batteries
Chang Su, Guoqiang Liu, Qiang Sun, Lei Wen, Zeyu Chen, Meiju Zhao
Abstract
The series P2-type Mn–Fe-based layered oxide materials (Na 2/3 Mn x Fe 1– x O 2 ) for sodium-ion batteries are regarded as potential commercial cathode materials due to their high specific capacity and low cost. However, the P2-type layered oxide cannot avoid some phase transformation during the charge–discharge process, which results in poor structural reversibility and low-capacity retention. Moreover, a high capacity usually means more insertion/extraction of Na +, which results in large changes in the lattice volume and poor cycling stability. Herein, a new strategy containing oxygen vacancies and Mg substitution is designed to obtain high-performance sodium storage of Mn–Fe-based layered oxide. The P′2-type Na 0.67 Mn 0.85 Fe 0.1 Mg 0.05 O 2−δ (Ovs & Mg-sub) cathode material is synthesized by the above-mentioned dual-modification strategy. The effect of oxygen vacancies and Mg substitution on the structural evolution during the charge–discharge process is further investigated by in situ X-ray diffraction techniques. It demonstrates that Ovs & Mg-sub has reversible structural transformation and smaller lattice volume changes, thus further exhibiting prominent electrochemical properties. The initial discharge specific capacity reaches 190.2 mAh g –1 at a current density of 20 mA g –1 and remains at 152.9 mAh g –1 at a current density of 100 mA g –1 after 100 cycles. In addition, it has a superior rate capability of 88.9 mAh g –1 at a current density of 2000 mA g –1 .