Photocatalytic oxidation of various C–H bonds by a polyoxometalate nanocluster-dominated compartmentalized metal–organic framework
Jiachen Jiao, Chuanbao Zhang, Hui Sun, Haina Hu, Ziqing Xu, Junwei Zhao, Qiuxia Han, Pengtao Ma
Abstract
A polyoxometalate nanocluster-dominated compartmentalized metal–organic framework (NiW12-TPT) was synthesized, which displays excellent performance in the photocatalytic oxidation of various hydrocarbons at room temperature with oxidant H 2 O and air.
Topics & Concepts
PolyoxometalatePhotocatalysisMetalChemistryMetal-organic frameworkPhotochemistryInorganic chemistryChemical engineeringCatalysisOrganic chemistryAdsorptionEngineeringPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis