Na<sub>3</sub>FeH<sub>7</sub> and Na<sub>3</sub>CoH<sub>6</sub>: Hydrogen-Rich First-Row Transition Metal Hydrides from High Pressure Synthesis
Kristina Spektor, Wilson A. Crichton, Stanislav Filippov, S. I. Simak, Andreas Fischer, Ulrich Häußermann
Abstract
establishes a consecutive series of homoleptic hydrogen-rich complexes for first-row transition metals from Cr to Ni.
Topics & Concepts
ChemistryHomolepticCrystallographyTetragonal crystal systemOrthorhombic crystal systemTransition metalHydrideTernary operationHydrogenAb initio quantum chemistry methodsX-ray crystallographyAb initioDisproportionationOctahedronMetalElectron diffractionPentagonal bipyramidal molecular geometryDiffractionCrystal structureMoleculeCatalysisComputer scienceOpticsPhysicsOrganic chemistryProgramming languageBiochemistryHydrogen Storage and MaterialsAdvanced Chemical Physics StudiesBoron and Carbon Nanomaterials Research