Photocatalytic deuterocarboxylation of alkynes with oxalate
Pei Xu, Hao-Qiang Jiang, Hui Xu, Sai Wang, Hui-Xian Jiang, Songlei Zhu, Long Yin, Dong Guo, Xu Zhu
Abstract
generated from oxalate played significant roles in realizing the global deuterocarboxylation of terminal and internal alkynes to access various tetra- and tri-deuterated aryl propionic acids with high yields and deuteration ratios.
Topics & Concepts
OxalatePhotocatalysisAlkyneCatalysisChemistryPhotoredox catalysisPhotochemistryCombinatorial chemistryOrganic chemistryChemical Reactions and IsotopesAmmonia Synthesis and Nitrogen ReductionFluorine in Organic Chemistry