One-step fabrication of fiber optic SERS sensors via spark ablation
Attila Kohut, Viktória Horváth, Zsuzsanna Pápa, Balázs Vajda, Judit Kopniczky, Gábor Galbács, Zsolt Geretovszky
Abstract
Spark ablation, a versatile, gas-phase physical nanoparticle synthesis method was employed to fabricate fiber-optic surface enhanced Raman scattering (SERS) sensors in a simple single-step process. We demonstrate that spark-generated silver nanoparticles can be simply deposited onto a fiber tip by means of a modified low-pressure inertial impactor, thus providing significant surface enhancement for fiber-based Raman measurements. The surface morphology of the produced sensors was characterized along with the estimation of the enhancement factor and the inter- and intra-experimental variation of the measured Raman spectrum as well as the investigation of the concentration dependence of the SERS signal. The electric field enhancement over the deposited silver nanostructure was simulated in order to facilitate the better understanding of the performance of the fabricated SERS sensors. A potential application in the continuous monitoring of a target molecule was demonstrated on a simple model system.