Experimental and computational studies on pseudotetrahedral nickel(<scp>ii</scp>)-(<i>S</i> or <i>R</i>)-dihalogen-salicylaldiminates with Δ- or Λ-chirality induction at-metal
Arezoo Saadati, Hadi Amiri Rudbari, Mahnaz Aryaeifar, Olivier Blacque, Isabel Correia, Mohammad Khairul Islam, Dennis Woschko, Takin Haj Hassani Sohi, Christoph Janiak, Mohammed Enamullah
Abstract
Synthesis of pseudotetrahedral bis[( S or R )-N-1-(phenyl)ethyl-(2,4-dihalogen-salicylaldiminato-κ 2 N,O)]-Δ/Λ-nickel( ii ), Δ/Λ-Ni( S or R )L 1–3 with Δ- or Λ-chirality induction at-metal.
Topics & Concepts
NickelChirality (physics)ChemistryMetalStereochemistryPhysicsQuantum mechanicsOrganic chemistryNambu–Jona-Lasinio modelChiral symmetry breakingQuarkMetal complexes synthesis and propertiesMagnetism in coordination complexesCrystal structures of chemical compounds