Kinetic Study of the Gas-Phase C(<sup>3</sup>P) + CH<sub>3</sub>CN Reaction at Low Temperatures: Rate Constants, H-Atom Product Yields, and Astrochemical Implications
Kevin M. Hickson, Jean‐Christophe Loison, Valentine Wakelam
Abstract
Rate constants have been measured for the C(3P) + CH3CN reaction between 50 and 296 K using a continuous-flow supersonic reactor. C(3P) atoms were created by the in situ pulsed laser photolysis of CBr4 at 266 nm, while the kinetics of C(3P) atom loss were followed by direct vacuum ultraviolet laser-induced fluorescence at 115.8 nm. Secondary measurements of product H(2S) atom formation were also made, allowing absolute H-atom yields to be obtained by comparison with those obtained for the C(3P) + C2H4 reference reaction. In parallel, quantum chemical calculations were performed to obtain the various complexes, adducts, and transition states relevant to the title reaction over the 3A″ potential energy surface, allowing us to better understand the preferred reaction pathways. The reaction is seen to be very fast, with measured rate constants in the range of (3–4) × 10–10 cm3 s–1 with little or no observed temperature dependence. As the C + CH3CN reaction is not considered in the current astrochemical networks, we test its influence on interstellar methyl cyanide abundances using a gas-grain dense interstellar cloud model. Its inclusion leads to predicted CH3CN abundances that are significantly lower than the observed ones.