Novel Filler-Filled-Type Polymer Electrolyte Membrane for PEFC Employing Poly(vinylphosphonic acid)-<i>b</i>-polystyrene-Coated Cellulose Nanocrystals as a Filler
Tomohiro Nohara, Toshihiko Arita, Keisuke Tabata, Takaaki Saito, Ryuichiro Shimada, Haruki Nakazaki, Yukina Suzuki, Ryota Sato, Akito Masuhara
Abstract
Low-acidity polymer electrolyte membranes are essential to polymer electrolyte fuel cells (PEFCs) and water electrolysis systems, both of which are expected to be next-generation energy and hydrogen sources. We developed a new type of high-performance polymer electrolyte membrane (PEM) in which the core particles are precisely electrolyte polymer coated and filled into binder resin. Cellulose nanocrystals (CNCs), which have attracted attention as light, rigid, and sustainable materials, were selected as the core material for the filler. The CNC surface was coated with a new block copolymer containing a proton conductive polymer of poly(vinylphosphonic acid) (PVPA) and a hydrophobic polymer of polystyrene (PS) using RAFT polymerization with particles (PwP) we developed. The pelletized fillers and the filler-filled polycarbonate membranes achieved proton conductivities of over 10–2 S/cm with lower activation energies and much weaker acidity than the Nafion membrane.