Rapid and accurate quality assessment method of recycled food plastics VOCs by electronic nose based on Al-doped zinc oxide
Valeriy Zaytsev, Fedor S. Fedorov, Boris Goikhman, Alexander Maslennikov, Vasilii Mashukov, Н. П. Симоненко, T. L. Simonenko, Dinara Gabdullina, О. V. Kovalenko, Е. П. Симоненко, Polina Kvitko, О. И. Пенькова, Дина Сатыбалдина, Shakhmaran Seilov, Tatiana S. Dubinina, Dmitry A. Gorin, Albert G. Nasibulin
Abstract
Plastic recycling technologies are being actively developed and implemented to cope with increasing volume of plastic. Such technologies require new analytical tools able to control the quality of the recycled polymers to be further integrated in production processes. Here, we propose a rapid and selective quality assessment method for polymer materials made of high-density polyethylene using electronic nose with aluminum doped zinc oxide sensing material in combination with the RandomForestClassifier machine learning tool. We test total content of volatile organic compounds both odor-active responsible for the smell and odorless of primary and secondary plastics, and evaluate corresponding organic vapors emitted by the plastics by headspace gas chromatography and mass-spectrometry at optimized conditions like sample temperature, sensor signal recovery time. The electronic nose demonstrated the good correlation of vector signal with the emitted volatile compounds with an accuracy more than 98.5% when discriminating between primary and secondary plastics. Addition of zeolites to the recycled plastic is shown to decrease the appearance of off-odors.