Redox-inactive ions control the redox-activity of molecular vanadium oxides
Simon Greiner, Benjamin Schwarz, Mark R. Ringenberg, Maximilian Dürr, Ivana Ivanović‐Burmazović, Maximilian Fichtner, Montaha Anjass, Carsten Streb
Abstract
can be used as an active material in lithium-ion cathodes. Our results show how redox-inert cations can be used as structural and electrostatic stabilizers, leading to major changes in the redox-chemistry of polyoxovanadates.
Topics & Concepts
RedoxVanadiumLithium (medication)Inorganic chemistryChemistryVanadium oxideIonLithium vanadium phosphate batteryCathodeInertHalf-reactionElectrochemistryElectrodeOrganic chemistryPhysical chemistryMedicineEndocrinologyPolyoxometalates: Synthesis and ApplicationsAdvanced battery technologies researchVanadium and Halogenation Chemistry