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Directionally-Grown Carboxymethyl Cellulose/Reduced Graphene Oxide Aerogel with Excellent Structure Stability and Adsorption Capacity

Mengke Zhao, Sufeng Zhang, Guigan Fang, Chen Huang, Ting Wu

2020Polymers50 citationsDOIOpen Access PDF

Abstract

-maleic acid)/poly (ethylene glycol) system via a directional freezing technique exhibits high structure stability while simultaneously maintaining its excellent adsorption capacity to remove organic dyes from liquid. A series of crosslinked aerogels with different amounts of GO were investigated for their adsorption capacity of methylene blue (MB), which were found to be superb adsorbents, and the maximum adsorption capacity reached 520.67 mg/g with the incorporation of rGO. The adsorption kinetics and isotherm studies revealed that the adsorption process followed the pseudo-second-order model and the Langmuir adsorption model, and the adsorption was a spontaneous process. Furthermore, the crosslinked aerogel can be easily recycled after washing with dilute HCl solution, which could retain over 97% of the adsorption capacity after recycling five times. These excellent properties endow the crosslinked CMC/rGO aerogel's potential in wastewater treatment and environment protection.

Topics & Concepts

AerogelAdsorptionCarboxymethyl celluloseGrapheneMaterials scienceLangmuir adsorption modelChemical engineeringEthylene glycolMethylene blueOxideEthylene oxideCelluloseOrganic chemistryChemistryComposite materialPolymerCopolymerNanotechnologyCatalysisSodiumPhotocatalysisEngineeringMetallurgyAerogels and thermal insulationAdvanced Sensor and Energy Harvesting MaterialsAdvanced Cellulose Research Studies
Directionally-Grown Carboxymethyl Cellulose/Reduced Graphene Oxide Aerogel with Excellent Structure Stability and Adsorption Capacity | Litcius