Post-synthetic linker installation: an unprecedented strategy to enhance iodine adsorption in metal–organic frameworks
Zi‐Jian Li, Yu Ju, Jie Qiu, Zhi‐Hui Zhang, Linjuan Zhang, Ming‐Yang He, Jian‐Qiang Wang, Jian Lin
Abstract
Post-synthetic linker installation in a single-crystal-to-single-crystal manner was crystallographically demonstrated in thorium-based metal-organic frameworks (Th-MOFs), not only leading to the discovery of an extremely rare framework de-interpenetration, but also representing an unprecedented strategy for boosting iodine adsorption capacity.
Topics & Concepts
LinkerMetal-organic frameworkAdsorptionBoosting (machine learning)IodineMetalNanotechnologyMaterials scienceLanthanideCrystal (programming language)Combinatorial chemistryChemistryChemical engineeringOrganic chemistryComputer scienceProgramming languageMachine learningEngineeringIonOperating systemMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsRadioactive element chemistry and processing