Self-Sacrificing Template of the POMs-Based Composite for the High-Performance Organic–Inorganic Hybrid Cathode of Lithium-Ion Batteries
Feng‐Cui Shen, Can Guo, Shengnan Sun, Zhen Lei, Ya‐Qian Lan
Abstract
The high theoretical capacity of vanadium oxides makes them promising cathode candidates for the rechargeable lithium-ion batteries (LIBs). Nevertheless, the relatively poor electrical conductivity and capacity retention hinder the practical application and have to be overcome urgently for the increasing demand for storage technologies. Herein, a new BRG system composed of bimetallic oxide/rhodamine B (RB)/reduced graphene oxide (RGO) was prepared through the facile self-sacrificing template of the precursor polyoxometalate (POM) composites POMs/RB/RGO (PRG). RB not only acts as a cationic mediator to facilitate the loading of POMs on graphene for conversion to oxides but also promotes the formation of uniform nanorods on the RGO. The prepared composite FeV3O8-RB/RGO-1 as the cathode exhibits superior cycling stability (specific capacity of 225 mA h g–1 at 100 mA g–1) and elastic rate capabilities for LIBs. What is more, the new PRG precursor provides versatile possibilities for the design of oxide composites from the self-sacrificing template of POMs-based composites with abundant architectural designs and compositions for the energy storage system.