Ba<sub>2</sub>BS<sub>3</sub>Cl and Ba<sub>5</sub>B<sub>2</sub>S<sub>8</sub>Cl<sub>2</sub>: first alkaline-earth metal thioborate halides with [BS<sub>3</sub>] units
Jiazheng Zhou, Yu Chu, Junjie Li, Shilie Pan
Abstract
Ba2BS3Cl and Ba5B2S8Cl2 have been synthesized by using PbCl2 as the flux and source of halogen. The two compounds show 3D network structures built by isolated [BS3] units with different Ba-S-Cl groups. This work enriches the structural diversity of boron chemistry and provides an insight into the synthesis of thioborates.
Topics & Concepts
Alkaline earth metalHalideChemistryMetalInorganic chemistryOrganic chemistryCrystal Structures and PropertiesIron-based superconductors researchInorganic Chemistry and Materials