Syntheses and characterizations of iron complexes of bulky <i>o</i>-phenylenediamide ligand
Qiuming Liang, Jack H. Lin, Joshua C. DeMuth, Michael L. Neidig, Datong Song
Abstract
We report the syntheses of a family of tetrahedral iron complexes bearing a bulky redox active o-phenylenediamide ligand. The electronic structures of these complexes have been investigated by Mössbauer spectroscopy, magnetic susceptibility measurements, and X-ray crystallography.
Topics & Concepts
Mössbauer spectroscopyLigand (biochemistry)CrystallographyChemistryRedoxMagnetic susceptibilityTetrahedronStereochemistryInorganic chemistryReceptorBiochemistryMagnetism in coordination complexesMetal-Catalyzed Oxygenation MechanismsOrganometallic Complex Synthesis and Catalysis