Photoinduced EDA complex triggered difluoroalkylation of quinoxalin-2(1 <i>H</i> )-ones with unactivated alkenes and fluoroalkyl bromides
Huanhuan Cui, Xiulin Qiao, Tiesheng Shi, Wei Wei, Huilan Yue, Zu‐Li Wang, Zhen Ma, Zi Yang
Abstract
A photo-induced three-component reaction of quinoxalin-2(1 H )-ones with unactivated alkenes and fluoroalkyl bromides has been developed. This transformation was initiated by the photochemistry of electron donor acceptor (EDA) complexes.
Topics & Concepts
ChemistryReaction conditionsAcceptorPhotochemistryCombinatorial chemistryElectron donorPolymer chemistryElectron acceptorReaction mechanismSurface modificationFunctional groupVisible spectrumOrganic chemistryCatalysisPalladiumAlkeneFluorine in Organic ChemistrySynthesis and Biological Evaluation